Phenyl Chloroformate CAS 1885-14-9 Purity ≥99.0% (GC)

Chemical Name: Phenyl Chloroformate Synonyms: Chloroformic Acid Phenyl Ester  CAS: 1885-14-9 Purity: ≥99.0% (GC) Appearance: Colorless Oily Liquid  Contact: Dr. Alvin Huang Mobile/Wechat/WhatsApp: +86-15026746401 E-Mail: alvin@ruifuchem.com

Products Details

Chemical Properties:

Package: Bottle, 25kg/Drum, 200kg/Drum, or according to customer's requirement. Storage Condition: Keep the container tightly closed and store in a cool, dry and well-ventilated warehouse away from incompatible substances. Protect from light and moisture. Shipping: Deliver to worldwide by air, by FedEx / DHL Express. Provide fast and reliable delivery. Shanghai Ruifu Chemical Co., Ltd. is the leading manufacturer of Phenyl Chloroformate (CAS: 1885-14-9) with high quality. Ruifu Chemical can provide worldwide delivery, competitive price, excellent service, small and bulk quantities available. Purchase Phenyl Chloroformate, Please contact: alvin@ruifuchem.com

Description:

Package/Storage/Shipping:

Chemical Name Phenyl Chloroformate 
Synonyms Chloroformic Acid Phenyl Ester; PCF
Stock Status In Stock, Commercial Production     
CAS Number 1885-14-9
Molecular Formula C7H5ClO2
Molecular Weight 156.57 g/mol
Boiling Point 187℃
Flash Point 76℃(169°F) 
Sensitive Moisture Sensitive, Heat Sensitive 
Water Solubility  Hydrolysis
Solubility  Soluble in Benzene, Chloroform, Ether
COA & MSDS Available
Sample  Available
Origin Shanghai, China
Brand Ruifu Chemical

Advantages:

How to Purchase? Please contact Dr. Alvin Huang: sales@ruifuchem.com or alvin@ruifuchem.com  15 Years Experience? We have more than 15 years of experience in the manufacture and export of a wide range of high quality pharmaceutical intermediates or fine chemicals. Main Markets? Sell to domestic market, North America, Europe, India, Korea, Japanese, Australia, etc. Advantages? Superior quality, affordable price, professional services and technical support, fast delivery. Quality AssuranceStrict quality control system. Professional equipment for analysis include NMR, LC-MS, GC, HPLC, ICP-MS, UV, IR, OR, K.F, ROI, LOD, MP, Clarity, Solubility, Microbial limit test, etc. SamplesMost products provide free samples for quality evaluation, shipping cost should be paid by customers. Factory AuditFactory audit welcome. Please make an appointment in advance. MOQ? No MOQ. Small order is acceptable. Delivery Time? If within stock, three days delivery guaranteed. TransportationBy Express (FedEx, DHL), by Air, by Sea. Documents? After sales service: COA, MOA, ROS, MSDS, etc. can be provided. Custom SynthesisCan provide custom synthesis services to best fit your research needs. Payment TermsProforma invoice will be sent first after confirmation of order, enclosed our bank information. Payment by T/T (Telex Transfer), PayPal, Western Union, etc. 

FAQ:

Stable Supply: Maintain reasonable stock    

Professional Service: One stop purchasing service

Technical Support: Technology solution available

Custom Synthesis Service: Ranged from grams to kilos

Fast Delivery: If within stock, three days delivery guaranteed

High Quality: Established a complete quality assurance system

Sufficient Capacity: Sufficient facilities and technicians

OEM Package: Custom package and label available

Specifications:

Items Inspection Standards Results
Appearance Colorless Oily Liquid (Visual) Colorless Oily Liquid 
Purity / Analysis Method  ≥99.0% (GC)  99.6% 
Phenol ≤0.20% (GC)  0.10%
Diphenyl Carbonate ≤0.20% (GC)  0.04%
Phosgene ≤0.05% <0.05%
Hydrogen Chloride ≤0.10% <0.10%
Density (20℃)  1.243~1.249 Complies 
Refractive Index n20/D  1.510~1.513 Complies 
Color ≤50 APHA Complies 
Infrared Spectrum Conforms to Structure Complies 
Conclusion The product has been tested & complies with the given specifications

1885-14-9 - Risk and Safety:

1885-14-9 - Application:

Hazard Symbols T+ - Very toxic Risk Codes R22 - Harmful if swallowed R26 - Very Toxic by inhalation R34 - Causes burns R41 - Risk of serious damage to eyes R38 - Irritating to the skin R29 - Contact with water liberates toxic gas R37 - Irritating to the respiratory system Safety Description S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 - After contact with skin, wash immediately with plenty of soap-suds. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S28A - UN IDs UN 2746 6.1/PG 2 WGK Germany 3 RTECS FG3850000 FLUKA BRAND F CODES 10-19-21 TSCA Yes Hazard Class 6.1 Packing Group II Toxicity LD50 orally in Rabbit: 1730 mg/kg LD50 dermal Rabbit 4880 mg/kgPhenyl Chloroformate (CAS: 1885-14-9) is an important organic synthesis intermediate, which is widely used in chemical synthesis and can be used as polymer catalyst, plastic modifier, fiber treatment agent, and intermediate of medicine and pesticide. Phenyl Chloroformate acts as a precursor of phenyl mixed anhydrides which are used in peptide coupling reactions. Phenyl Chloroformate serves as a dehydrating reagent for the conversion of primary amides to nitriles and an intermediate in the synthesis of pharmaceuticals and carbamates. 

1885-14-9 - General Description:

Phenyl Chloroformate appears as a colorless liquid with a strong odor. Corrosive. Toxic by ingestion, inhalation and skin absorption. Very irritating to skin and eyes. Used as a reagent for organic synthesis.

1885-14-9 - Air & Water Reactions:

Emits fumes containing HCl in moist air. Decomposes in water to form HCl.

1885-14-9 - Reactivity Profile:

Phenyl Chloroformate is incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

1885-14-9 - Health Hazard:

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

1885-14-9 - Fire Hazard:

Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.

1885-14-9 - Production Method:

Phenyl Chloroformate is obtained by reacting phenol with phosgene. Phenol was dissolved in chloroform, and phosgene was introduced under cooling to add equimolar N,N-dimethylaniline Dropwise while stirring at 5-10℃., so that the amount of the absorbed phosgene was equimolar to that of phenol. Then diluted with cold water, the oil layer was separated and washed with dilute hydrochloric acid and water successively. After drying with anhydrous calcium chloride, chloroform was distilled off, and then distilled under reduced pressure to collect a fraction of 74-75℃. (1.73kPa), I .e., Phenyl Chloroformate. The yield was about 90%.

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